Yes, if you join the "230" terminal of the primary to the "0" terminal of the secondary, and feed 230v AC mains to the primary, you will get 420v out across the "0" terminal of the primary to the "190" terminal of the secondary.
[Note that when a transformer is wired as an autotransformer, pri-to-sec isolation is lost, so the output will be live.]
[Note that when a transformer is wired as an autotransformer, pri-to-sec isolation is lost, so the output will be live.]