The only suitable gaseous extinguishant would be CO2, there are calculations under the standards for unenclosed areas usually used for things like industrial fryers. With CO2 you need 43%by volume in an enclosed space like a switch room, leakage can be allowed for with a simple dalculation based on the size of openings. But with the volumes involved and the asphixiant risks, youould require some kind of interlocking system to stop it going off when manned. Or you could adopt a manual only system like ships have, where multiple actions need to be completed to drop the gas.
agreed, and fire protection is along side my usual profession, HVAC and fire protection go hand in hand, so know the craic regarding calculations, pressure and concentration level requirements.. However this old shed, would like trying to presurise Wembley stadium.. forget it, more holes than a political manifesto...
As you said the better (more viable) option would be sprinklers / water mist. It might happen eventually, easy enough to do, and I've been considering it for a while, dry sprinkler pipework installed through out piped to a solenoid on the mains water incomer, a total electrical shutdown (supply feeder is external) from a confirmed fire signal from any two out of three smoke or heat detectors (already installed) then from the same signal to a timed automatic release via the solenoid, overide key switch to manual during the day (to avoid any spurious release), switch to automatic out of hours. We'll see, would be a good project.. not that I don't have enough already eh !!