Directly weather compensated domestics will normally ramp up the flow temp on a hot water demand sign to overcome this issue.The most important temperature is that of the return water to the boiler. The lower it is, the better the temperature difference to the heat source and therefore the higher the heat transfer. It follows that lowering the flow temperature will help but you always need to know what your system was designed to operate at. Conventionally heating was designed to operate with 80 C flow and either 70 or 60 C return and the radiators would be selected to suit. Condensing systems are often designed with a flow of 60 C and a return of 40 C which gives a good compromise between boiler efficiency and radiator sizes (in a house with modern high insulation levels). If you subsequently reduce the flow temperature then the heat output from the radiators drops considerably ( look at radiator selection data from the manufacturers and there will be a whole load of correction factors to apply to the outputs for differing temperature. These are based on the difference of the mean water temperature to the space temperature). This is why underfloor heating is good with condensing boilers as it will probably have a maximum flow temperature of 45 C and a corresponding very low return temperature and hence the boiler will operate continuously in its condensing mode and therefore very highest efficiency.
Also important to ensure that the flow temperature remains sufficiently high to heat the domestic hot water if this is provided by a cylinder.
Would be interested to see the details of the Hive thermostat if you have them.