Modern automotive electronics should be designed to withstand quite high voltage spikes (I want to say around a couple hundred volts, but it's been a long time since I've read the relevant standards), however not for a sustained length of time.
Anything older (I'd guess over 20 years old), isn't likely to offer that level of protection, so connecting a desulphation spiker isn't likely to them much good, especially circuits at the cheaper end of the spectrum, such as clocks and aftermarket alarms.
Yes, I'd always assumed that the low internal impedance of a 75Ah lead-acid would soak up the spikes long before the electronic devices saw them.Fortunately the starter battery is a pretty good smoothing capacitor, so will absorb the spikes (as intended), it's not a great idea to have a charger on a desulphation phase connected with the ignition on though.
Personally, I've never had any issues, the spike will be around 20-35VDC max, charger dependent and of a duration of <10mS, that said, I've never connected one to anything older than 2007.
It's worth remembering that an alternator, especially a 'dumb' one can spike upwards of 50VDC for anything up to 500mS when an engine rpm goes high enough for it to kick in and the starter battery voltage is low enough for the alternator to go full output - especially when the jump pack/leads are removed....
Ask any late 90's Jaaag owner ;-)
