Some of that plate looks like it has a protective coating on it, that should be ground off if it has, or even better get some plain mild steel.
The dark sooty deposits suggest you are not getting sufficient gas coverage, it could be the dirty steel but I think the gas.
There are a couple of tidy runs there but until you get some clean metal to play with you will struggle to get where you hope to with the standard of finish.
Don't bother trying to join plates until you can put a very tidy run down on a single sheet of metal.
you need to clean the metal up for starters mig doesn't like dirty or rusty metal
what is the mig what settings etc are you using a auto mask ?