Don't wire in the immersion what ever you do. They use loads of electricity.Ours is setup so the oil boiler and the Rayburn are open. Boiler wont work in a powercut so that wont be a problem. The Rayburn is gravity feed so no pump needed therefore we still have hot water in a powercut but no central heating*). The pumps are for the boiler and central heating, with a third pump to send heat from the top of the store to the bottom if the top gets to 85C (this dissipates the heat and makes the central heating pump come on sooner. Its a clever setup. The central heating pump is designed to circulate when its thermostat kicks in (set at 55C in the winter) - as the Rayburn is on all the time, it makes sense to just constantly keep the house warm. Can ramp up or down circulation by loading the Rayburn or letting the fire die down a bit and slowing the burn. The oil boiler is for top ups if needed but we didnt turn it on at all last winter! My only criticism is that the store is probably a little small for the big bath with only the Rayburn heating it so we either need a 20 minute blast with the boiler to top the heat up or to add a second pre-heat tank to it. We didnt go larger as we didnt want to overdo the weight.
*not the biggest deal as the Rayburn and lounge log burner are fairly central in the house so only the bedrooms are cooler in a powercut and that just needs an extra duvet. One day i might run a lead so i can power the pumps with a generator if ever needed but its not a big deal.
We have the attachments to add solar water and there is an immersion fitted but not wired in so we could run that off of PV or mains if ever needed. The idea is to get the solar doing the work in the summer so we use less oil then.