Silicone is used to ruin the shape and feel of ladies funbags [/pedantic], silicon (and a little Mn) added to copper lowers the melting temp, improves mechanical properties and helps 'mop up' any oxides
Thinner material = thinner wire... with TIG the heat source is waaaay more focused/concentrated than with oxyfuel making it more difficult to melt and wet out the wire without melting the base material if the wire is too big. While 1.6mm is usable on 0.9 - 1.1mm sheet steel, 1.2mm silcopper or phosphorbronze makes life easier. On thicker stuff can just feed more of a thinner wire to build up a larger fillet or whateverHow would you select filler rod diameter. Cheers.