Do you mean this stuff?It's not silicone, it is laid as a thick bead on the outside of windows and doors to fill the gap between them and the brickwork?
then u finish of with frame sealant . a flexible sealerSometimes expanding foam is used for big gaps, and cut off after its set.
The gap is upto 8mm in places.
I've used Fosroc Nitoseal-ms60, it is serious stuff that can seal big gaps, but it's not easy to get and pricey.
that's minor when u see certain traveling folk cladding peoples housesFoam the gap, trim the foam once set, then seal with silicone. 8mm is not a large gap to seal.